6I1. - Bruker IFS 66 v/S Fourier-transform spectrometer, Spectral ranges:
MIR: 400 to 8000 cm-1
FIR: 450 to 80 cm-1
Elipsometers:
6E1. - J.A. Woollam M2000UI, Variable angle spectroscopic ellipsometer, rotating compensator, Spectral range: 0.73 to 5.13 eV
Spectrometers:
6S1. - UV-Vis spectrometer, Perkin-Elmer, Lambda 25, Transmission(i.e. extinction) and Reflectivity, two-beam spectrometer Optical region: wavelength 200 nm – 1100 nm, resolution: approx. 1nm 6S2. - UV-Vis spectrometer, Perkin-Elmer, Lambda 19, Transmission(i.e. extinction) and Reflectivity, two-beam spectrometer, Optical region: wavelength 200 nm – 3000 nm, resolution: approx. 1nm, Limited data transfer due to obsolete software and corresponding operating system. 6S3. - L.O.T. Shamrock -Grating spectrometer equipped with CCD-detectors (visible region & NIR-region, Andor inc.), Optical characterisation, depending on chosen setup: Transmission, fluorescence; can be attached to optical microscope to investigate microscopic regions, e.g single nanoparticle light scattering or confined sample regions, Optical region: wavelength 200 nm – 3000 nm, resolution: 0.2 -- 1nm depending on chosen diffractive optics.
Microscopes
6M1. - Digital Instruments Dimension 3100, Atomic force microscope 6M2. - Olympus BX 61, Optical microscope, Equipped with objectives up to 100x magnification, bright-field/ dark-field, immersion microscopy (optional), transmission/ reflected-light microscopy; motorized stage; video camera 6M3. - Bruker Hyperion, Optical + IR microscope, ATR-imaging, mapping, objectives up to 36x 6M4. - Neaspec s-SNOM, scattering-type scanning near field optical microscope, atomic force microscope
1. Microspectroscopy of nanosized / nanostructured samples: Combination of grating spectrometer and optical (dark-field)microscope enables the spectroscopic measurement of microscopic sized sample regions, e.g. scattering characteristics of single nanoparticles, see e.g. [3]
a) (optional) simultaneous laser-irradiation with the laser-light sources mentioned above, e.g. for photochemical/photochromic investigations
b) (optional) optical tweezers setup for immobilizing and positioning of nanoparticles within an aqueous suspension
c) planned: SERS-spectroscopy
2. UV-Vis spectroscopy: Spectroscopic measurement of slabs/ layer systems / thin films / suspensions
a) (optional) varying angle of incidence (no suspensions)
b) (optional) for suspensions: temperature dependent 5°C – 100 °C
c) (optional) simultaneous laser-irradiation with the laser-light sources mentioned above, e.g. for photochemical/photochromic/photothermal treatment
Microscopy
Expertise in optical microspectroscopy techniques in the visible regime of the light spectrum. Please, see “Spectroscopy – (1)” above
References:
[1] Reismann et al. Reversible Photothermal Melting of DNA in DNA-Gold-Nanoparticle Networks. Small (2008) vol. 4 (5) pp. 607-610
[2] Dahmen et al. Optical and structural changes of silver nanoparticles during photochromic transformation. Appl. Phys. Lett. (2006) vol. 88 (1) pp. 011923-3
[3]Sönnichsen et al. Drastic reduction of plasmon damping in gold nanorods. Phys. Rev. Lett. (2002) vol. 88 (7) pp. 077402
Table: Expertise by material type and sample geometry combinations:
Single Metal nanoparticles or nanoparticle systems
Aqueous suspensions of nanoparticles or nanoparticle systems (see [1]):
R,T,optical
R,T,A, optical
S, Ch infrared
R,T,S, optical
S, Ch infrared
Notation used here:
Frequency range: MHz, GHz, THz or optical R - reflection coefficient amplitude or intensity; T - transmission coefficient or intensity, P - phase information; A - reflection and transmission on many angles of incidence; E - ellipsometry data; D - ray velocity direction or distortion (do not mix, please, with isotropic refraction index characterization); S - internal structure investigation with microscopy (nanoscopy); Ch - chemical properties investigation (metal or dielectric etc.); Chi(2)/Chi(3) of the material
References:
[1] Reismann et al. Reversible Photothermal Melting of DNA in DNA-Gold-Nanoparticle Networks. Small (2008) vol. 4 (5) pp. 607-610
[2] Dahmen et al. Optical and structural changes of silver nanoparticles during photochromic transformation. Appl. Phys. Lett. (2006) vol. 88 (1) pp. 011923-3